Diffusion of n-hexane in high-density polyethylene
(HDPE) particulates was studied by nitrogen
purging of a hexane-permeated HDPE sample in a small glass cell.
By monitoring the decrease
in hexane concentration in the cell exit gas, the diffusivity of hexane
in HDPE was obtained.
The method does not require any alteration of the original HDPE
specimen and allows both the
intrinsic and effective diffusivities to be determined. Intrinsic
diffusion data measured for HDPE
powder and pellets using this method were compared with those from HDPE
sheets to show the
unique diffusion characteristics of the powder. Experimental
results at various purge flows
revealed that the effective hexane diffusivity in the HDPE powder
increased with gas purge
velocity before reaching a plateau representing the intrinsic
diffusivity. The low effective
diffusivity values at low purge velocities can be attributed to
particle agglomeration in the powder.
The effective diffusivity data for unaltered powder samples have
great practical significance in
characterizing industrial powder dryers.