2010
DOI: 10.1016/j.molstruc.2010.03.050
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Matrix isolation investigation of the ozonolysis of propene

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Cited by 14 publications
(10 citation statements)
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References 29 publications
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“…Beyond these papers from the astrochemical literature are several older matrix-isolation studies, such as the UV photolyses of propylene isolated in argon (Guillory & Thomas 1975) and of O 3 +propylene trapped in argon (Coleman & Ault 2010), and also the thermal chemistry of O 3 +propylene mixtures trapped in xenon (Andrews & Kohlmiller 1982). To the extent that comparisons are possible, our work is consistent with all of these studies, but differs in not using rare-gas matrices.…”
Section: Relationship To Previous Worksupporting
confidence: 69%
“…Beyond these papers from the astrochemical literature are several older matrix-isolation studies, such as the UV photolyses of propylene isolated in argon (Guillory & Thomas 1975) and of O 3 +propylene trapped in argon (Coleman & Ault 2010), and also the thermal chemistry of O 3 +propylene mixtures trapped in xenon (Andrews & Kohlmiller 1982). To the extent that comparisons are possible, our work is consistent with all of these studies, but differs in not using rare-gas matrices.…”
Section: Relationship To Previous Worksupporting
confidence: 69%
“…Both twin jet and merged jet arrangements were used as matrix sample deposition modes to explore different time scales for reaction. , In twin jet deposition, the two gas reactants were deposited simultaneously onto the CsI window from two separate nozzles allowing for only a very short mixing time prior to matrix formation. Samples were deposited on the window for about 24 h before a final spectrum was recorded.…”
Section: Methodsmentioning
confidence: 99%
“…Experimentally observed blank spectra were in good agreement with literature recorded spectra, 41,42 and with blanks run previously in this laboratory. 34,43 The blank experiment of each reagent was irradiated using a H 2 O/Pyrex filtered output of a 200 W Hg arc lamp for 1.0 h, and no changes were noted.…”
Section: ■ Experimental Sectionmentioning
confidence: 99%
“…Additional reaction time is available in this mode compared to twin jet and has led to ''late'' thermal reaction products in previous studies [26,36,37]. Nonetheless, relatively stable ''early'' intermediates may survive through the reaction zone and be trapped in the argon matrix.…”
Section: Discussionmentioning
confidence: 99%