In this paper we investigate generalized theta divisors Θr in the moduli spaces UC(r, r) of semistable vector bundles on a curve C of genus 2. We provide a desingularization Φ of Θr in terms of a projective bundle π : P(V) → UC (r − 1, r) which parametrizes extensions of stable vector bundles on the base by OC . Then, we study the composition of Φ with the well known theta map θ. We prove that, when it is restricted to the general fiber of π, we obtain a linear embedding.