Solar radiation exposure at work is a relevant heath risk in the construction sector. Our objective was to monitor for a full month the individual solar ultraviolet radiation (UVR) exposure of a group of three construction workers active in Siena (latitude = 43°19′ N), a town in Tuscany (Italy). We used personal electronic dosimeters “X-2012-10” (Gigahertz, Turkenfeld, Germany) to register the UV irradiance in the UVA and UVB/C regions separately and we consulted a specific database to retrieve the corresponding ambient erythemal UVR dose (cloud-free conditions). In spring, construction workers from central Italy received a quite variable UVR dose, between 0.9 standard erythemal doses (SED) and 15.6 SED/day, 5.7 on average. Considering the proportion with respect to the potential environmental exposure, personal exposure resulted between 2.7% and 31.2% of the ambient erythemal dose, with a mean value of 12.5%. Cumulatively, the three construction workers received in one working month a UVR dose of more than 120 SED. In a year, we estimated that a construction worker from Tuscany region is exposed to about 750 SED. This data demonstrates that construction workers in Italy are exposed to extremely high levels of solar UVR, with a relevant risk of developing adverse health effects related to the potential accumulation of UVR-induced damage in susceptible biological tissues, such as the skin and the eyes.