Measurement of 151Sm in nuclear decommissioning samples by ICP-MS/MS

Miranda, Maria Garcia; Russell, Ben; Ivanov, P.

doi:10.1007/s10967-018-5764-x

Cited by 14 publications

(9 citation statements)

References 20 publications

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“…Research fields and objectives. The research fields of the above references covered biology, 1-15 energy, 16 environment, 9,[17][18][19][20][21][22][23][24][25][26][27][28][29][30][31][32] food/medical, 10-12,25-27,33-40 geology, 28,41-47 material, [48][49][50][51][52][53][54][55][56][57][58][59][60] and radionulide, 4,[22][23][61][62][63][64][65][66][67][68][69][70][71] respectively. In addition to these conventional elemental analysis topics, a study on the gas phase catalytic reaction has also been reported by using the reaction cell of ICP-QMS/QMS as the in-situ reaction field.…”

Section: References Investigatedmentioning

confidence: 99%

“…Many references used He, H2, O2, or NH3, which are usually included as the default cell gas for ICP-QMS/QMS. 4,22,26,44,46,[62][63][64][65][66] There are also multiple references using N2O, 3,23,28,45,68 CO2, 24,27,65 or CH4 43 as the cell gas to improve the separation of spectral interferences. For single element solution, the typical relative uncertainty of isotopic ratio obtained by ICP-QMS/QMS is roughly in the range from 0.1% to 0.2%, which is inferior to that can be achieved by multiple collector (MC-) ICP-MS by 3 to 4 orders of magnitude.…”

Section: Reaction Gases Used In the Measurement By Icp-qms/qmsmentioning

confidence: 99%

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Trends and Advances in Inductively Coupled Plasma Tandem Quadruple Mass Spectrometry (ICP-QMS/QMS) With Reaction Cell

Zhu¹

2021

At.Spectrosc.

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Trends and advances in the development and application of inductively coupled plasma tandem quadrupole mass spectrometry (ICP-QMS/QMS) with a reaction cell is reviewed mainly based on publications from January 2018 to July 2021. ICP-QMS/QMS has been applied in various research fields covering the sciences of biology, energy, environmental, food/medical, geology, materials, and radionuclide. The objectives of analysis cover the determination of elemental concentration, ion-gas reaction, isotope analysis, single particle analysis, and chemical speciation analysis. Measurement of most elements in the periodic table are reported except for H, N, O, F, rare gas, and some of the radionuclides. In addition to the default reaction/collision gases (i.e., He, H2, O2, and NH3), N2O, CO2, CH4, CH3F, C2H4, and C2H6 have been used as reaction gases to improve the capability of separating spectral interferences or to study the ion-molecule reactions. Typical applications of ICP-QMS/QMS analysis in the major research fields are also discussed.

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Section: References Investigatedmentioning

confidence: 99%

Section: Reaction Gases Used In the Measurement By Icp-qms/qmsmentioning

confidence: 99%

Trends and Advances in Inductively Coupled Plasma Tandem Quadruple Mass Spectrometry (ICP-QMS/QMS) With Reaction Cell

Zhu¹

2021

At.Spectrosc.

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show abstract

“…These authors determined 87 Sr/ 86 Sr ratios directly in certified geological reference materials, BCR‐2 and BHVO‐2, with a precision below 0.1% RSD. The results also showed that the 87 Sr/ 86 Sr ratios of 23 different rock types measured by ICP‐MS/MS and MC‐ICP‐MS methods agreed very well, demonstrating the potential of this method not only in geological studies, but also in other related areas such as environment, agriculture, and nuclear science studies 111,166,175,176,177 . Thus ICP‐MS/MS is set to make greater contributions in geochemical, geochronological, and mineral exploration studies, avoiding the necessity of using a matrix‐matched standard for calibrations.…”

Section: Technological Advances For the Removal Of Interferences In Imentioning

confidence: 68%

Strategies to overcome interferences in elemental and isotopic geochemical analysis by quadrupole inductively coupled plasma mass spectrometry: A critical evaluation of the recent developments

Balaram

2021

Rapid Comm Mass Spectrometry

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Quadrupole Inductively Coupled Plasma Mass Spectrometry (ICP‐MS) instruments were introduced into geochemical and mineral exploration laboratories nearly four decades ago, providing a technique that could meet their longstanding requirement for the precise and accurate determination of several groups of trace elements and isotopes in geological materials such as rocks, minerals, ores, soils, sediments, and natural water samples. Despite its popularity among geochemists, the technique suffered from spectral and non‐spectral interferences some of which seriously affected the quality of the data generated. These interferences have also had a significant impact on the ability of ICP‐MS systems to achieve low detection limits. Over the last three decades, technical advances such as the development of high‐resolution (HR)‐ICP‐MS, cool plasma, collision/reaction cell technology (CCT), dynamic reaction cell (DRC) technology, collision reaction interface (CRI), kinetic energy discrimination (KED), tandem mass spectrometry (ICP‐MS/MS)/triple quadrupole ICP‐MS, and multi‐quadrupole ICP‐MS have been introduced to eliminate/minimize many of these interferences, with each technique having its strengths and limitations. These technologies have extended the range of elements that can be measured accurately not only in geological materials, but also in several other matrices, with lower detection limits than before. In addition, other methods such as internal standardization, isotope‐dilution, standard addition and matrix‐matching calibrations have contributed to improving the quality of the data. This paper provides a review of these new developments from the geochemical analysis point of view.

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“…Nickel-63 is measurable by LSC following chemical separation, achieved by dimethylglyoxime (DMG) precipitation, anion exchange and/or extraction chromatography. [19][20][21][22][23][24] Whilst not being a focus of this study, there is additional interest in measurement of longer lived 59 Ni (half life 76 (5) Â 10 3 a), which has the potential to be a powerful forensic tool through measurement of 59 Ni/ 63 Ni isotopic ratios. Whilst theoretically measurable, 59 Ni suffers from signicant tailing ( 58 Ni), polyatomic ( 58 Ni 1 H) and isobaric ( 59 Co) interferences and there is no known ICP-MS procedure for measuring this radionuclide.…”

Section: Measurement Of Standardsmentioning

confidence: 99%

Development of a single method for direct measurement of multiple radionuclides using ICP-MS/MS

Russell

Warwick

Mohamud

et al. 2023

J. Anal. At. Spectrom.

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Measurement of 151Sm in nuclear decommissioning samples by ICP-MS/MS

Cited by 14 publications

References 20 publications

Trends and Advances in Inductively Coupled Plasma Tandem Quadruple Mass Spectrometry (ICP-QMS/QMS) With Reaction Cell

Trends and Advances in Inductively Coupled Plasma Tandem Quadruple Mass Spectrometry (ICP-QMS/QMS) With Reaction Cell

Strategies to overcome interferences in elemental and isotopic geochemical analysis by quadrupole inductively coupled plasma mass spectrometry: A critical evaluation of the recent developments

Development of a single method for direct measurement of multiple radionuclides using ICP-MS/MS

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