Measurement of Electrical Conductivity in Molten Fluorides. A Survey

Robbins, G.D.

doi:10.1149/1.2412059

Cited by 30 publications

(15 citation statements)

References 24 publications

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“…A short review of conductivity methods in molten salts is available ( 178). An extensive review of the measurement of electrical conductivity of 56 molten fluoride systems has appeared (232).…”

Section: Ch3co-nh2mentioning

confidence: 99%

Titrations in nonaqueous solvents

Lagowski¹

1970

Anal. Chem.

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Section: Ch3co-nh2mentioning

confidence: 99%

Titrations in nonaqueous solvents

Lagowski¹

1970

Anal. Chem.

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“…As demonstrated by Robbins (1969) and by coworkers (1971, 1972) the measured resistance can be considered to include the true solution resistance (R ) and a polarization resistance which is inversely proportional to the square root of the applied frequency, R = R + kuT 1 / 2 (2) meas s The cell constant is determined by using a liquid with a known conductivity.…”

Section: General Remarksmentioning

confidence: 99%

Specific Electrical Conductivities of Electrolytes Used in Three Layer Refining of Aluminium

Thonstad

Jarek

Müftüoglu

et al. 1987

Proceedings of the International Symposium on Quality and Process Control in the Reduction and Casting of Aluminum and Other Li

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“…Volume 48, Number may become quite large relative to unity, requiring the calculation of Rs from RBr, CB> and u> (7,15,29). For a 10-ohm resistance, the error of assuming R, = RB> would be 3%.…”

Section: Balance Of Pure Resistancesmentioning

confidence: 99%

“…In molten salt conductance measurements the approximation Rb< = Rs in Figure 5b frequently is not valid because of the low resistance, especially for corrosive melts which cannot be contained in capillary cells, but must be measured in crucible-type cells with low cell constants (29). Failure to make the appropriate calculation of Rs from RB> and CB' (or an erroneous correction resulting from flaws in the bridge) may lead to spurious frequency dispersion.…”

Section: Application To Special Systems Molten Saltsmentioning

confidence: 99%

Electrolytic conductance measurements and capacitive balance

Braunstein¹,

Robbing²

1971

J. Chem. Educ.

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Paper No. 110. 1 The term ionic constituent refers to the ion-forming portion of an electrolyte, without specification of the extent of dissociation, association, solvation, etc. See, e.g., reference (4), p. 60. Thus the ionic constituents in an aqueous solution of CdR are Cd! + and I-, regardless of the fact that, the actual species in solution may include hydrated cadmium ions, anionic complexes such as Cdl4!_, etc. Measurements of macroscopic properties yield information only on the components (Cdl-j and water) or the ionic constituents. Unusual values of these properties may suggest the microscopic nature of the species (e.g., ions). More detailed information on the nature of the species requires measurements sensitive to the species properties and distribution (e.g., spectra).Alternative methods of conductance measurement are pointed out, as are some aspects pertinent to the measurement of dielectric constant. The extent of coverage can easily be modified to suit the level of the course and the time available.Phenomenology: Ohm's Law Applied to Electrolytes rent occurs whether the system be liquid, solid, or gaseous, single component or multicomponent. (See reference (47)).

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Measurement of Electrical Conductivity in Molten Fluorides. A Survey

Cited by 30 publications

References 24 publications

Titrations in nonaqueous solvents

Titrations in nonaqueous solvents

Specific Electrical Conductivities of Electrolytes Used in Three Layer Refining of Aluminium

Electrolytic conductance measurements and capacitive balance

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