The development of an autocorrelator based on a two-photon absorption of a photomultiplier photocathode is described. A solar-blind photomultiplier, sensitive in the far-ultraviolet region, is used to detect a two-photon absorption in the near-ultraviolet region. Such an autocorrelator can be used to measure the pulsewidth of a laser ͑396 nm, 110 fs͒ produced by the second harmonic generation of a Ti:sapphire laser.An ultrashort optical pulse has recently attracted the attention of researchers in the fields of spectroscopy and material processing. However, there is no established method for the measurement of the pulse width of a laser in the ultraviolet region. Although an autocorrelator based on frequency doubling using a nonlinear optical crystal is routinely used in the visible and near-infrared regions, no crystal is available that is transparent and which can be phase matched in the vacuum ultraviolet region. Therefore, an ultraviolet laser pulse is sometimes measured based on a third harmonic generation, although the efficiency is rather poor. 1 Several alternate approaches have been proposed to date for the measurement of the pulse width of the ultraviolet femtosecond laser. For example, the multiphoton ionization of a lowpressure gas in a static cell can be utilized as a nonlinear optical detector. 2 Pulse width measurements have also taken advantage of a two-photon absorption and subsequent fluorescence detection using a thick diamond plate. 3 A crosscorrelation signal arising from the multiphoton ionization of argon or helium in a supersonic jet has also been employed in pulse width measurements. 4 Unfortunately, these methods are somewhat complicated and are not convenient for use as a routine method. Thus, the development of an autocorrelator that is simple and easy to operate in laser pulse width measurements in the ultraviolet region would be desirable. Alternatively, a sensitive autocorrelator, based on the two-photon absorption of a photomultiplier photocathode, has been reported for such measurements in the near-infrared region. 5 This approach requires no phase matching and is easy to operate for use in routine work.In this study, we describe the construction of an autocorrelator consisting of a solar-blind photomultiplier, which is one-photon sensitive in the far-ultraviolet region, for measurement of a laser pulse width based on a two-photon absorption in the near-ultraviolet region.In order to evaluate the two-photon absorption of a photomultiplier photocathode, a Z-scan experiment, schematically shown in Fig. 1, was performed. In this experiment, the fundamental beam of a Ti:sapphire laser ͑Thales, 100 fs, 1 mJ, 1 kHz͒ is frequency doubled using a -barium borate crystal ͑thickness, 1.6 mm͒ and is utilized as a laser source. The intensity of the laser can be changed roughly by inserting a neutral density filter and finely by rotating a polarizer. The laser power was monitored by means of a power meter ͑Molectron, PM10͒. The laser beam is focused by a lens with a focal length of 10 cm. The t...