For mixed-field radiation detection, abundant characteristic
signatures
can be obtained through the detection of both neutron and γ-rays,
which brings a huge challenge for high-efficiency detection of neutrons
and γ-rays by using a single scintillator. Unfortunately, commercial
organic scintillators show good performance for neutron detection
but lack the sensitivity to detect γ-rays, whereas inorganic
scintillators show the opposite behavior. Herein, two-dimensional
lithium-doped phenylethylammonium lead bromide (Li-(PEA)2PbBr4) perovskite single crystals were reported for mixed-field
radiation detection. Abundant hydrogen, lithium, and heavy lead atoms
enabled a large cross section toward neutrons and γ-rays. The
Li-(PEA)2PbBr4 exhibited a bright blue emission
peak at 434 nm, a fast decay time of 10.5 ns, a high light yield of
∼29 000 photons/MeV, and a light yield nearly 9 times
higher than that of the plastic scintillator EJ200 under α excitation.
The sensitivity was 2.55 × 10–14C per γ-ray
under 60Co excitation. It also showed an excellent response
toward neutrons with a wide range of energy, and the sensitivities
were 2.29 × 10–14C per neutron (14.1 MeV) and
1.93 × 10–14C per neutron (2.5 MeV). Moreover,
Li-(PEA)2PbBr4 exhibited better spatial resolutions
in high-energy pulsed X-ray (2 lp/mm) and neutron (1 lp/mm) imaging
applications. These results indicate the favorable ability of Li-(PEA)2PbBr4 in mixed-field radiation detection.