Conduction and breakdown have been studied in the boundary regions of wall-stabilized arc columns for arc currents up to 50 A in N2, Ar, He, air and SF6 at atmospheric pressure, and for stabilizing hole diameters of 5 and 4 mm. In the case of SF6 no electrons could be drawn to a positively charged disk, and this is shown to be due to the unusual property of an SF6 plasma below 4000°K, namely that it comprises only positive and negative ions (S+ and F−). Estimates of temperature on the plasma side of the boundary layer, based on the magnitudes of the positive-ion currents, vary from 2800°K in SF6 to 4800°K in N2 for 25 A arcs in 5 mm diameter holes. Some characteristics of unipolar arcs, which are defined as arcs which join a metallic electrode to a plasma, are given for Ar and SF6.