“…14, one can see a fair coincidence of our results with the results of [9] in the domain of adiabatic energies for the cross-sections a3C._O22-N2 (C) and a3C_O22-He (E). The divergence in the results for the crosssection a3c.~176 (C) can be explained by the fact that the parameter a in [9] used for calculating this cross-section varied in the range (1-5).10 -5 , which, as one can see in Fig. 6, corresponds to the deviation error ~(a) = 2.10-z _ 10-z.…”
Section: Analysis Of the Results Of Calculationssupporting
confidence: 82%
“…6, corresponds to the deviation error ~(a) = 2.10-z _ 10-z. This means that, for increasing the accuracy of the cross-section calculation in [9], it is necessary to investigate a wider range of variation of the parameter a. From Fig.…”
Section: Analysis Of the Results Of Calculationsmentioning
confidence: 99%
“…The norms (7) and (8) The practical use of norms (5)- (8) given above for obtaining the parameter r in different model examples [8] and examples of solving the problems of the physical-chemical kinetics of the molecular interaction [9][10][11][12][13] shows that selection of the parameter c~ is not unique, because usually there are several values CZrnin, for which the norms given above have an extremum (minimum) or have no extreme points at all. In [8], it is proposed, in particular, to use the following empirical rule --to choose the value Oemi n related to the second right-hand-side minimum.…”
Section: Criterion Selection Of the Regularization Parametermentioning
confidence: 99%
“…In [9], the parameter a was defined by the condition of minimum of the continuous norm for the zero regularization q = 1 and p = O.…”
Section: Calculation Of Cross-sectionsmentioning
confidence: 99%
“…For the first time, the regularization method was applied for calculating the cross-sections in [9,10] where…”
The inverse problem method for elementary processes in physical-chemical kinetics is developed. By using experimental values of the velocity constants determined in a limited temperature range, cross-sections of
“…14, one can see a fair coincidence of our results with the results of [9] in the domain of adiabatic energies for the cross-sections a3C._O22-N2 (C) and a3C_O22-He (E). The divergence in the results for the crosssection a3c.~176 (C) can be explained by the fact that the parameter a in [9] used for calculating this cross-section varied in the range (1-5).10 -5 , which, as one can see in Fig. 6, corresponds to the deviation error ~(a) = 2.10-z _ 10-z.…”
Section: Analysis Of the Results Of Calculationssupporting
confidence: 82%
“…6, corresponds to the deviation error ~(a) = 2.10-z _ 10-z. This means that, for increasing the accuracy of the cross-section calculation in [9], it is necessary to investigate a wider range of variation of the parameter a. From Fig.…”
Section: Analysis Of the Results Of Calculationsmentioning
confidence: 99%
“…The norms (7) and (8) The practical use of norms (5)- (8) given above for obtaining the parameter r in different model examples [8] and examples of solving the problems of the physical-chemical kinetics of the molecular interaction [9][10][11][12][13] shows that selection of the parameter c~ is not unique, because usually there are several values CZrnin, for which the norms given above have an extremum (minimum) or have no extreme points at all. In [8], it is proposed, in particular, to use the following empirical rule --to choose the value Oemi n related to the second right-hand-side minimum.…”
Section: Criterion Selection Of the Regularization Parametermentioning
confidence: 99%
“…In [9], the parameter a was defined by the condition of minimum of the continuous norm for the zero regularization q = 1 and p = O.…”
Section: Calculation Of Cross-sectionsmentioning
confidence: 99%
“…For the first time, the regularization method was applied for calculating the cross-sections in [9,10] where…”
The inverse problem method for elementary processes in physical-chemical kinetics is developed. By using experimental values of the velocity constants determined in a limited temperature range, cross-sections of
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.