Measurement of vapor–liquid equilibrium for binary mixtures of phenol–dimethyl carbonate and phenol–methanol at 101.3kPa

Hu, Wang-Ming; Shen, Lv-Ming; Zhao, Lu-Jun

doi:10.1016/j.fluid.2004.01.023

Cited by 15 publications

(4 citation statements)

References 4 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…Hu and Cheng 27 used methyl salicylate and ethyl benzoate as entrainers to separate the azeotrope. Hu et al 31 explored the effect of phenol on the relative volatility of the azeotrope; Kim et al 32 and Zhu et al 33 investigated the effects of different types and concentrations of ionic liquids on the thermodynamic behavior of the azeotropic mixture of DMC and methanol, respectively. Zhang et al 34 measured the VLE data of the mixture (methanol + dimethyl sulfoxide) at 101.3 kPa.…”

Section: Introductionmentioning

confidence: 99%

Isobaric Vapor–Liquid Equilibrium Measurements of Binary Systems of Dimethyl Carbonate with Dimethyl Sulfoxide, Anisole, and Diethyl Oxalate at 101.3 kPa

et al. 2021

View full text Add to dashboard Cite

In this work, three entrainers were selected to separate the azeotrope of dimethyl carbonate (DMC) and methanol, which were dimethyl sulfoxide, anisole, and diethyl oxalate. The vapor–liquid equilibrium (VLE) data of four binary systems (DMC + dimethyl sulfoxide, DMC + anisole, DMC + diethyl oxalate, and methanol + diethyl oxalate) were measured using a modified Rose-type circulating still at 101.3 kPa. The Van Ness point-to-point test and infinite dilution test were used to test the thermodynamic consistency of the experimental VLE data. The nonrandom two-liquid, universal quasi-chemical, and Wilson models were used to correlate the measured VLE data. The binary interaction parameters of the three models were regressed.

show abstract

Section: Introductionmentioning

confidence: 99%

Isobaric Vapor–Liquid Equilibrium Measurements of Binary Systems of Dimethyl Carbonate with Dimethyl Sulfoxide, Anisole, and Diethyl Oxalate at 101.3 kPa

et al. 2021

View full text Add to dashboard Cite

show abstract

“…Actually, many literatures ,, have used the concept of activity, which can describe the vapor–liquid equilibrium (VLE) behavior in the development of kinetic model to modify the effect of the mass transfer. Unfortunately, only the VLE data of binary systems (methanol + DMC, DMC + phenol, methanol + phenol, MPC + methanol, and MPC + DMC) have been determined at atmospheric pressure in the past decades. − There has been no data reported about DPC up to now. That is to say, to calculate the accurate activity coefficients of all transesterification species, the reported VLE data are not enough.…”

Section: Resultsmentioning

confidence: 99%

Kinetic Modeling of the Transesterification Reaction of Dimethyl Carbonate and Phenol in the Reactive Distillation Reactor

Yin

Zeng

Yao

et al. 2014

Ind. Eng. Chem. Res.

View full text Add to dashboard Cite

The kinetic behavior of preparing diphenyl carbonate by the transesterification of dimethyl carbonate with phenol in a reactive distillation reactor has been explored experimentally and theoretically. The transesterification reaction was described to conform a pseudo-second-order kinetics, and a semi-empirical kinetic model has been derived to explain the kinetic behavior. The model parameters were fitted to experimental data by an improved genetic algorithm. The proposed model was determined to be useful in simulating the rate constant and the mole fraction of components, which agreed well with the experimental data for different operating temperatures and catalyst concentrations.

show abstract

“…26 and not used for the statistical analysis. Some predicted gas-phase compositions have a large (up to 0.45 mole fraction) deviation from the values available in the literature (particularly, [125,138]). We believe this is partially caused by the model limitations.…”

Section: Vle With Alcoholsmentioning

confidence: 88%

Evaluation of experimental and predicted vapor-liquid equilibrium data for systems relevant to biomass fast pyrolysis and catalytic upgrading

Paulechka¹,

Diky²,

Dutta³

2021

View full text Add to dashboard Cite

The experimental vapor-liquid equilibrium (VLE) data for the binaries relevant to the catalytic fast pyrolysis of biomass have been collected and analyzed using the NIST-COSMO-SAC and NIST-modified UNIFAC models. The existing inconsistencies in the experimental data and the predicted values are discussed. For VLE with furan derivatives, PTxy data are normally reported, and the predicted values are in good agreement with them. For phenolic compounds, the gas phase compositions are available for only 36 % of the points, most results originate from a few laboratories, and each system has been typically studied in a single laboratory. The binaries are identified where more experimental VLE data are required to evaluate quality of the existing experimental and predicted results.

show abstract

Measurement of vapor–liquid equilibrium for binary mixtures of phenol–dimethyl carbonate and phenol–methanol at 101.3kPa

Cited by 15 publications

References 4 publications

Isobaric Vapor–Liquid Equilibrium Measurements of Binary Systems of Dimethyl Carbonate with Dimethyl Sulfoxide, Anisole, and Diethyl Oxalate at 101.3 kPa

Isobaric Vapor–Liquid Equilibrium Measurements of Binary Systems of Dimethyl Carbonate with Dimethyl Sulfoxide, Anisole, and Diethyl Oxalate at 101.3 kPa

Kinetic Modeling of the Transesterification Reaction of Dimethyl Carbonate and Phenol in the Reactive Distillation Reactor

Evaluation of experimental and predicted vapor-liquid equilibrium data for systems relevant to biomass fast pyrolysis and catalytic upgrading

Contact Info

Product

Resources

About