A new solidification process called non-interfacial-gap permanent-mold casting (NIGPMC) is proposed to improve the cooling rate by eliminating the metal-mold interfacial gap. High-Cr steel ingots were prepared by this process and conventional permanent-mold casing (CPMC) separately. Comparing with CPMC, the primary dendrite arm spacing obtained by NIGPMC is greatly refined. It is demonstrated that the NIGPMC is a promising pathway to refine the microstructure of the large ingot.A higher cooling rate is desired in the solidification processes because materials fabricated under this condition have several benefits, such as finer microstructure, extended solid solubility, improved strength, and better corrosion behavior. [1][2][3][4] It is known that the cooling rate is directly determined by the heat transfer which is regulated not only by the heat storage capacity of the mold material, but also by the heat transfer conditions within the metal itself and particularly at the metalmold interface. [1] To date, the investigations performed for improving cooling rate are mostly focused on the former using the water-cooled copper mold and the phasetransition-materials-cooled copper mold. [1,5] However, there are few studies on enhancing the heat transfer at the metal-mold interface.The heat extraction capacity of the metal-mold interface can be characterized by the metal-mold interfacial heat transfer coefficient (IHTC) that is a power function of time [6] :where h is the IHTC in units of W/m 2 K, t is time in seconds, and C i and n are constants depending on alloy composition, chill material, and superheat. In general, the IHTC shows a high value in the initial stage of solidification and then declines to a low steady value because the casting contracts from the mold surface, creating an interfacial gap. According to the truth that the reduction of the interfacial gap could increase the IHTC and the cooling rate, [6][7][8] we developed a new solidification process as NIGPMC to obtain a higher cooling rate. The key point of the new method is the introduction of a melt-mold, made of low-melting-point materials, which can be melted to eliminate the interfacial gap during solidification. For a better understanding of this process, we also studied the CPMC and quantificationally investigated the macro-and microstructure. Figure 1 presents the schematics of the conventional permanent-mold and the NIG permanent-mold. In these two processes, both of the permanent-molds are made of H13 steel with the chemical composition (wt pct) 0.4 C, 1.0 Si, 0.4 Mn, 5.1 Cr, 1.3 Mo, and 1.0 V. In the NIGPMC, the melt-mold is made of 6061 aluminum alloy with chemical composition (wt pct) 0.3 Cu, 1.0 Mg, 0.12 Mn, 0.25 Zn, 0.04 Cr, 0.6 Si, and 0.7 Fe. The sizes of these molds are also shown in Figure 1. In order to further clarify the mechanism of the NIGPMC, a K-type thermocouple was inserted into the melt-mold for recording the temperature profile.A high-Cr steel X12CrMoWVNbN10-1-1 (refer to X12 hereafter) with the chemical composition (wt pct)...