[1] The long-lived daughter products of 222 Rn ( 210 Pb,210 Bi, and 210 Po) in the atmosphere have been utilized to obtain residence time and transport time scale of atmospheric aerosols. Residence times obtained using 210 Bi/ 210 Pb consistently yielded lower residence times compared to 210 Po/ 210 Pb pair. This is widely attributed to the extraneous sources of 210 Po. However, one additional source that has been overlooked is the decay from 210 Bi. Most of the published data that reports residence time of aerosols based on 210 Po/ 210 Pb pair do not report corrections in 210 Po activities due to its in-growth from 210 Bi. In this work, we quantitatively evaluate the effect of initial 210 Bi concentrations in the atmospheric aerosol filters at the time of collection on the production rates of 210 Po and how that could affect the residence time calculated using 210 Po. In particular, we estimate the deviation of in situ 210 Po activities from the measured 210 Po activities for two limiting extreme cases: (1) neglecting the initial 210 Bi concentrations and (2) assuming secular equilibrium between 210 Bi and 210 Pb. The residence times under these scenarios have been calculated. Our results show that neglecting the value of the initial 210 Bi concentration in air can lead to significant differences between the in situ 210 Po activity and measured 210 Po, and thus affect the residence time calculations of the aerosols. Therefore, 210 Bi should be determined when 210 Po measurements are carried out in air, and 210 Bi/ 210 Pb pair should be utilized better than 210 Po/ 210 Pb one in order to estimate aerosol residence time.Citation: Lozano, R. L., E. G. San Miguel, and J. P. Bolívar (2011), Assessment of the influence of in situ 210 Bi in the calculation of in situ 210 Po in air aerosols: Implications on residence time calculations using 210 Po/ 210 Pb activity ratios,