<p>In
recent years solar geoengineering has been proposed as
a
promising strategy to contrast global warming induced by anthropogenic CO<sub>2</sub>
emissions.
These technologies design to inject in the stratosphere
massive
amounts of molecular species, which can act as precursors for aerosol
formation able to partially reflect sunlight. SO<sub>2</sub>
is
one of these species. Since
in
the atmosphere
several
natural ionization sources, such as cosmic rays and corona discharge,
are active, we have considered that SO<sub>2</sub><sup>+</sup>
ions
can be formed in the stratosphere in a significant amount
after
being injected by balloons or
aircrafts. The
SO<sub>2</sub><sup>+
</sup>chemistry
could play a role in the dynamics of
aerosol formation as a cooling agent. We
have studied theoretically and experimentally
the
reaction of SO<sub>2</sub><sup>+</sup>,
produced by tunable synchrotron radiation, with H<sub>2</sub>
leading
to HSO<sub>2</sub><sup>+</sup>
and
H, the latter being
involved
in the ozone depletion by producing O<sub>2
</sub>and
OH. This is an ionic possible alternative
to OH formation during the nighttime, when
the common sunlight process of OH generation cannot
occur. In
order to explain the experimental reactivity we propose a new
non-thermal version of the Variational Transition State Theory. We
provide
analytic
expressions
for
the
temperature
dependent
rate
coefficients, which
should
be tested in
atmospheric kinetic models to fully explore the stratospheric solar
geoengineering strategies.</p>