Terahertz time-domain
spectroscopy in a transmission geometry combined
with visual analysis was used to investigate the crystallization process
of MgSO
4
solution. Careful spectral analysis of both a
feature at 1.6 THz and the overall magnitude of absorption allowed
the extraction of information about the liquid phase before and during
crystallization, aiding the investigation of solvation dynamics and
the behavior of molecular species at phase boundaries. The method
was reproducibly applied to a number of measurements on a series of
solutions of three chosen concentrations at different temperatures.
When increasing temperature at the end of the measurement, the dissolution
of crystals was observed as well. The temperature-dependent absorption
data of the semicrystalline systems were converted to the solvent
concentrations using a recently developed method. Solutions of a series
of concentrations were also investigated in the temperature range
of 4–25 °C. The results were compared to the theoretical
calculated values, and the consistent differences proved the existence
of a hydration shell around the salt ions whose behavior is different
from bulk water. Future work will focus on triggering nucleation at
specific positions in order to study the very beginning of the crystallization
process. MgSO
4
heptahydrate is used as a model system in
this study, while the concept and the setup can be applied to other
systems.