In addition to the in-situ measurements, flask samples are taken at Ochsenkopf at approximately weekly intervals and are subsequently analysed for the mixing ratios of the same species, as well as H 2 , and the stable isotopes, δ 13 C, δ 18 O in CO 2 . The in-situ measurements of CO 2 and O 2 from 23 m show substantial diurnal variations that are modulated by biospheric fluxes, combustion of fossil fuels, and by diurnal changes in the planetary boundary layer height. Measurements from 163 m exhibit only very weak diurnal variability, as this height (1185 m a.s.l.) is generally above the nocturnal boundary layer. CH 4 , CO, N 2 O and SF 6 show little diurnal variation even at 23 m owing to the absence of any significant diurnal change in the fluxes and the absence of any strong local sources or sinks. From the in-situ record, the seasonal cycles of the gas species have been characterized and the multi-annual trends determined. Because the record is short, the calculation of the trend is sensitive to inter-annual variations in the amplitudes of the seasonal cycles. However, for CH 4 a significant change in the growth-rate was detected