High-peak-power lasers are fundamental to high-field science: increased
laser intensity has enabled laboratory astrophysics, relativistic
plasma physics, and compact laser-based particle accelerators.
However, the meter-scale optics required for multi-petawatt lasers to
avoid light-induced damage make further increases in power
challenging. Plasma tolerates orders-of-magnitude higher light flux
than glass, but previous efforts to miniaturize lasers by constructing
plasma analogs for conventional optics were limited by low efficiency
and poor optical quality. We describe a new approach to plasma optics
based on avalanche ionization of atomic clusters that produces plasma
volume transmission gratings with dramatically increased diffraction
efficiency. We measure an average efficiency of up to 36% and a
single-shot efficiency of up to 60%, which is comparable to key
components of high-power laser beamlines, while maintaining high
spatial quality and focusability. These results suggest that plasma
diffraction gratings may be a viable component of future lasers with
peak power beyond 10 PW.