Abstract. The thermal conductivity, κ, of nylon-6 increased 22% whereas the heat capacity per unit volume, ρc p , decreased 10% by adding 2.1 wt% Multi-Wall Carbon Nanotubes MWCNTs. Simultaneously, the glass transition temperature, T g , which was detected as a weak sigmoidal increase in ρc p and a decrease in dκ/dT, increased 11 K. These results show that the MWCNTs-nylon-6 interaction restricts the segmental mobility of nylon-6 and decreases c p of nylon-6.