An indoor accelerated freezing and thawing test of polypropylene fibre-reinforced concrete in chloride and sulphate environments was conducted using the “fast-freezing method” with the objective of investigating the damage law of the post-freezing mechanical properties of hydraulic concrete structures and studying the effects of different mixing amounts of polypropylene fibres on the mechanical properties of concrete. Furthermore, in order to reduce the cost of concrete tests and shorten the time required for conducting concrete tests, a backpropagation neural network based on a Beetle Antenna Search algorithm (BAS-BPNN) was established to simulate and predict the mechanical properties of polypropylene fibre-reinforced concrete. The accuracy of the model was verified. The results indicate that the order of improvement in the macro-physical properties of concrete due to fibre doping is as follows: PPF1.2 exhibited the greatest improvement in macro-physical properties of concrete, followed by PPF0.9, PPF1.5, PPF0.6, and PC. When the freezing and thawing medium and the number of cycles are identical, all four assessment indexes (R2, RMSE, SI, MAPE) demonstrate that the four groups of polypropylene fibre concrete exhibit superior performance to the control group of ordinary concrete. This indicates that polypropylene fibre can enhance the mechanical properties and freezing resistance of the concrete matrix, delay the process of freezing and thawing damage to the matrix, and extend the lifespan of the matrix, yet cannot prevent the ultimate failure of the matrix. The application of intelligent algorithms to optimise the parameters of an artificial neural network model can enhance its capacity to generalise and predict the mechanical properties of concrete. In terms of the coefficient of determination (R2), the Beetle Antenna Search algorithm (0.9782) outperforms the Particle Swarm Optimization (PSO; 0.9676), the Genetic Algorithm (GA; 0.9645), and the backpropagation neural network (BPNN; 0.9460). The improved backpropagation neural network based on the Beetle Antenna Search algorithm not only avoids the trap of local optimality but also improves the model accuracy while further accelerating the convergence speed. This approach can address the complexity, non-linearity, and modelling difficulties encountered during the freezing process of concrete. Moreover, it offers relatively accurate prediction outcomes at a reduced cost in comparison to traditional experimental methodologies.