Abstract. The effect of temperature on weldline properties of injection moulded acrylonitrile butadiene styrene (ABS) reinforced with short glass fibres was investigated in tension between 25 and 100°C. Tensile modulus of both weld and unweld specimens increased linearly with increasing fibre concentration and decreased linearly with increasing temperature. It was found that the presence of weldline had no significant effect upon tensile modulus and this was reflected by weldline integrity factors in the range 0.98 to 0.95. Tensile strength of both weld and unweld tensile specimens increased nonlinearly with increasing fibre concentration and in the case of weldline specimens showed a maximum at fibre concentration of approximately 10% v/v. A linear dependence with respect to volume fraction of fibres was found for specimens without weldline for fibre concentrations in the range 0-10% v/v. The weldline integrity factor for tensile strength decreased significantly with increasing fibre concentration and increased with increasing temperature. The effect of temperature on tensile modulus and strength was satisfactorily modelled using the Kitagawa power law relationship. Vol.1, No.10 (2007) [688][689][690][691][692][693][694][695][696][697] Available online at www.expresspolymlett.com DOI: 10.3144/expresspolymlett.2007.94 being used. For example, whilst addition of spherical shaped fillers (e.g. glass spheres) has shown to have little effect upon tensile strength of injection moulded thermoplastics with weldlines, addition of cylindrical shaped fillers (e.g. short fibres) has led to a considerable reduction in weldline strength due to the alignment of the fibres parallel to the weldline. The processing conditions such as melt temperature, injection speed and mould temperature could also play an important role in determining the integrity of the welded components and many studies have addressed this issue for both amorphous and semi-crystalline polymers (e.g.: [10,11,14])]. However, whilst the majority of weldline studies have been conducted at room temperature, very few have examined the integrity of weldlines at elevated temperatures, particularly in short fibre composite systems [3][4][5]. To this end, the present work was undertaken to examine the effect of temperature on tensile properties of ABS and its short glass fibre composites in the presence of weldline.
Keywords: polymer composites, weldline, temperature eXPRESS Polymer Letters
Experimental
MaterialsOwens Corning chopped E-glass fibres of initial length and diameter of 4.0 mm and 10 μm, respectively was used as the reinforcing filler for Acrylonitrile Butadiene Styrene (ABS) copolymer received from BAYER. The ABS and the short glass fibres were compounded to produce a series of composites with nominal glass contents of 10, 20 and 30% w/w.
CompoundingABS and the short glass fibres were at first dry blended to the desired glass contents of 10, 20 and 30% w/w. After drying in an oven at 80°C for 4 hours the melt compounding of ABS composites was carri...