In this work the effect of cyclic butylene terephthalate (CBT) was studied on the curing, rheological, morphological and mechanical properties of styrene butadiene rubber (SBR)
IntroductionProperties of rubbers can be tailored upon requirements for a wide range of application fields. Their ability to withstand large deformation both under compression and tension without cracking and their damping capability are those specific features which are exploited in products' design. However, these noteworthy and outstanding properties over plastics are accompanied by some drawbacks, such as complex compound formulations and complicated processing. A wide variety of rubbers and additives are used in rubber industry to adjust the performance of compounds to meet given specifications. Further, the effects of certain additives are adverse to those of others. Therefore, to reach balanced properties (e.g. mechanical behaviour, wear resistance, processability) is a very challenging task. Cured unfilled synthetic rubbers show poor mechanical and wear properties, therefore various fillers (usually inorganic mineral fillers and carbon black) -among others -are incorporated into the recipes. Regrettably, these fillers significantly increase the viscosity of the rubber mixtures, thereby hampering their processability. In order to compensate this issue various types of processing aids and plasticizers are used. However, usually they have a negative effect on the mechanical properties. The application of an additive lacking this opposing effect would have great research potential. Our research strategy was to find an additive which is able to reduce the viscosity of the uncured compounds significantly and works as reinforcement in the cured rubber.Cyclic butylene terephthalate oligomer (CBT) is a cyclic oligoester that polymerizes in situ in the presence of suitable catalysts at high temperatures (>140°C) via ring-opening polymerization [1,2]. This makes CBT a suitable matrix material of various micro- [3,4] and nanocomposites [5,6]. Further advantage of CBT as a matrix material for composites is linked with its very low melt viscosity, which facilitates the appropriate impregnation of the reinforcing structure. However, the polymerized cyclic butylene terephthalate (pCBT) is more brittle than conventional polybutylene terephthalate (PBT) produced by polycondensation. This is caused by the fact that pCBT exhibits higher molecular weight and crystallinity than PBT.