Marine biofouling presents numerous challenges, including increased drag, reduced efficiency, and ecological imbalance. This review presents an overview of recent advances in antifouling coatings. First, essential preparation techniques such as cold spray, plasma spray, magnetron sputtering, and laser cladding are introduced, including the specific characteristics of each method. Next, the antifouling performance of Cu-doped and Ag-doped coating is analyzed. Emphasis is placed on the differences in coating composition, preparation methods, and their effects on antifouling and anticorrosion properties. The future development of antifouling technologies is also discussed, emphasizing the creation of multifunctional coatings, the optimization of coating microstructures for better performance, and the advancement of sustainable materials to minimize environmental impact.