This study aimed at improving hardness, wear resistance, and fracture toughness by tempering chromium carbide (Cr 3 C 2 )/carbon steel surface composites fabricated by high-energy electronbeam irradiation. The mixture of Cr 3 C 2 powders and MgF 2 flux was placed on a plain carbon steel substrate, and then electron beam was irradiated on this mixture using an electron-beam accelerator. In the specimens fabricated with flux powders, the surface composite layer of 1.9 mm in thickness was successfully formed without defects, and contained about 3 vol pct of Cr 7 C 3 carbides in the matrix composed of plate-type martensite and austenite. When the Cr 3 C 2 / steel surface composite was tempered, the martensite was resolved, and Cr 7 C 3 carbides were coarsely precipitated along cell boundaries while the austenite disappeared, thereby leading to the increase in hardness and wear resistance. Observation of the microfracture process of the 500°C-tempered surface composite revealed that cracks initiated and propagated along intercellular Cr 7 C 3 carbides and stopped propagating when they met the relatively ductile tempered martensite matrix. Accordingly, this composite showed improved fracture toughness and presented good application possibilities as hard and tough wear-resistant materials.