Evaporating seawater and separating salt from water is one of the most promising solutions for global water scarcity. Stateâofâtheâart water desalination devices combining solar harvesting and heat localization for evaporation using nanomaterials still suffer from several issues in energy efficiency, longâterm performance, salt fouling, light blocking, and clean water collection in realâworld applications. To address these issues, this work devises plasmaâenabled multifunctional allâcarbon nanoarchitectures with onâsurface waterways formed by nitrogenâdoped hydrophilic graphene nanopetals (NâfGPs) seamlessly integrated onto the external surface of hydrophobic selfâassembled graphene foam (sGF). The NâfGPs simultaneously transport water and salt ions, absorb sunlight, serve as evaporation surfaces, then capture the salts, followed by selfâcleaning. The sGF ensures effective thermal insulation and enhanced heat localization, contributing to high solarâvapor efficiency of 88.6 ± 2.1%. Seamless connection between NâfGPs and sGF and selfâcleaning of NâfGP structures by redissolution of the captured salts in the waterways lead to longâterm stability over 240 h of continuous operation in real seawater without performance degradation, and a high daily evaporation yield of 15.76 kg mâ2. By eliminating sunlight blocking and guiding condensed vapor, a high clean water collection ratio of 83.5% is achieved. The multiple functionalities make the current nanoarchitectures promising as multipurpose advanced energy materials.