Enhancing the corona resistance of epoxy resin (EP) is crucial for ensuring the reliable operation of electrical equipment and power systems, and the incorporation of inorganic nanofillers into epoxy resin has shown significant potential in achieving this. In this study, functionalized graphene oxide (KHGO) was synthesized via a sol-gel method to enhance the corona resistance of EP with electrochemical impedance spectroscopy (EIS) used to assess the properties of KHGO/EP composites. Fourier transform infrared spectroscopy (FTIR) and X-ray photoelectron spectroscopy (XPS) verified the successful grafting of epoxy groups onto the GO surface. The thermal conductivity and stability of the KHGO/EP composite initially increased with KHGO content but declined when the content exceeded 1.2 wt.%. Positron annihilation lifetime spectroscopy (PALS) indicated that KHGO improved interfacial compatibility with EP compared to GO, with agglomeration occurring when KHGO content exceeded a threshold value (1.2 wt.%). EIS analysis revealed that the corona resistance of the KHGO/EP composite was optimal at a filler content of 0.9 wt.%. After corona treatment, the saturation water uptake of the 0.9 wt.% KHGO/EP composite decreased by 15% compared to pure EP with its porosity reduced to just 1/40th of that of pure EP. This study underscores that well-dispersed KHGO/EP composite exhibits excellent corona resistance property suggesting the potential for industrial applications in high-voltage equipment insulation.