2016
DOI: 10.1002/cctc.201600167
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Mechanism and Origin of Selectivity in Platinum(II)‐Catalyzed Reactions of Acyclic γ,δ‐Ynones with Alkenes

Abstract: The generation of platinum‐containing carbonyl ylides from acyclic γ,δ‐ynones and the cycloaddition of these ylides with electron‐rich alkenes have been explored computationally to explain the experimentally observed regio‐ and stereoselectivity. Three pathways for the reaction of ylides with methyl vinyl ether have been investigated. Two of these involve [3+2] cycloadditions, whereas the third involves a [4+2] cycloaddition. Results indicate that the operative reaction pathway depends on the substitution patt… Show more

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