1997
DOI: 10.1007/bf01668512
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Mechanism of oxygen dissolution in metallic zirconium

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Cited by 10 publications
(2 citation statements)
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“…Similar results on the dissolution of oxygen into Zr during oxidation has been reported by other researchers as well. 24,25 From our earlier atomic-resolution electron-energy-loss spectroscopy work on zirconia, it was found that a substoichiometric layer about 1-1.5 nm thick was formed towards the metal-oxygen interface while the buried interface consisted of zirconia of composition closer to the stoichiometric oxide. 22 Therefore, the metal-dissolved oxygen mixture is shown to be at the metal-oxygen interface in Fig.…”
Section: Resultsmentioning
confidence: 99%
“…Similar results on the dissolution of oxygen into Zr during oxidation has been reported by other researchers as well. 24,25 From our earlier atomic-resolution electron-energy-loss spectroscopy work on zirconia, it was found that a substoichiometric layer about 1-1.5 nm thick was formed towards the metal-oxygen interface while the buried interface consisted of zirconia of composition closer to the stoichiometric oxide. 22 Therefore, the metal-dissolved oxygen mixture is shown to be at the metal-oxygen interface in Fig.…”
Section: Resultsmentioning
confidence: 99%
“…When this system is held at high temperature, first the native oxide of silver Ag 2 O decomposes into Ag and O 2 above 725 K [47,48] and the native zirconium oxide ZrO 2 dissolves into the Zr as the solubility for O is relatively high at T < 970 K [49,50]. Ag and Zr then react at the contact points, which occurs by the nucleation of intermetallic compounds in accordance with the Ag-Zr binary diagram.…”
Section: Model Of Surface Reconstructionmentioning
confidence: 99%