Mechanism of ruthenium-catalyzed linear dimerization of acrylonitrile: a deuterium labelling study

Tsou, D.T.; Burrington, James D.; Maher, Eamonn; Grasselli, Robert K.

doi:10.1016/0304-5102(83)80084-4

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Cited by 12 publications

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“…8) although controversy remains as to the involvement of such a mechanism (ref. 9). (3) In 1978, Yamazaki, Sonogashira, and Hagihara reported catalytic addition of benzene to the double bond of a ketene using Rh4(CO)12 as the catalyst (eq.…”

Section: Introductionmentioning

confidence: 99%

Catalytic Addition of C-H Bonds to Multiple Bonds. The First Stage.

Murai

1994

J. Syn. Org. Chem., Jpn.

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Section: Introductionmentioning

confidence: 99%

Catalytic Addition of C-H Bonds to Multiple Bonds. The First Stage.

Murai

1994

J. Syn. Org. Chem., Jpn.

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Transition‐Metal‐Catalyzed π‐Bond‐Assisted CH Bond Functionalization: An Emerging Trend in Organic Synthesis

Gandeepan

2015

Chemistry An Asian Journal

174

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Transition-metal-catalyzed C - H activation is considered to be an important tool in organic synthesis and has been accepted and widely used by chemists because it is straightforward, cost-effective, and environmentally friendly. A variety of functional groups have been used to direct metal complexes and achieve regioselective C - H activation. Most directing is achieved through the σ-bond coordination of functional groups to the metal catalyst, followed by ortho-selective C - H bond cleavage. However, recent work has demonstrated that π-coordinating functional groups can also assist in guiding metal complexes for site-selective C - H bond activation. This emerging approach significantly expands the scope of C - H activation reactions in organic synthesis. Herein, recent developments in this field are summarized.

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