We discovered that optical vortices with an annular spatial form and an orbital angular momentum owing to a helical wave front enable us to twist materials, such as metal, silicon and azo-polymer, to form various structured matters including microneedles, chiral nanostructures and chiral surface reliefs. Such structured matters will potentially open the door to advanced devices, for instance, silicon photonic device, biomedical microelectro-mechanical systems, ultrasensitive detector for chiral chemical composites and plasmonic metasurfaces for chiral chemical reactions.