“…processes involving the coupling of alkynylruthenium complexes and tetracyanoethylene [1015]. A computational study of ruthenium acetylides connected to dithienylperfluorocyclopentene groups focused on protonation, redox processes, and NLO properties [1016]. Metal vinylidene complexes were suggested as likely M a n u s c r i p t 106 intermediates in the ruthenium-catalyzed reductive anti-Markovnikov hydration of terminal alkynes and formic acid [1017].…”