A study was carried out to investigate the effect of hydrodynamic variables and exposure time on the corrosion of copper in a 4.6-M lithium bromide (LiBr) solution at room temperature using electrochemical techniques. The corrosion rate, measured in terms of the corrosion current density (i corr ), increased with the Reynolds number following a potential relation typical of processes controlled by the mass transport of the species formed in the dissolution process through the corrosion product film and the diffusion boundary layer, the effect of erosion caused by the particles of the corrosion product being negligible. In the range of the fluid velocities investigated, the corrosion potential (E corr ) shifted to more noble values, and the passivating current density decreased with the increase in fluid velocity as a result of the stabilization of the passive film formed. Over the exposure period, E corr and i corr increased sharply, reaching a maximum on the first days of exposition. After this time, E corr and i corr decreased, exhibiting slight fluctuations around a mean value.