“…Among mechanical milling techniques, solid-state shear milling (S 3 M) technology has the advantages of wide applicability, convenient operation, high efficiency, simplicity, energy saving, and no pollution 24 and can be used for grinding, mixing, and hydrochemical reactions of polymers and fillers. 25,26 At present, this technology has been widely used in polymer microgrinding preparation, Lai et al 27 used S 3 M technology to achieve rubber decrosslinking and recycling, furthermore, the reclaimed products via thermoplastic re-processing had excellent mechanical properties, and the optimal stress and strain were increased by 208.2% and 269.4%, respectively, compared with the products made from virgin scraps, this is a great progress. Zhang et al 28 used S 3 M technology to improve the crystallinity, thermal and mechanical properties of PVDF/graphene composites, realizing the exfoliation of graphene as well as the solid grafting of graphene layers on PVDF molecules, improving the dispersion of graphene layers in PVDF and making them effectively exert their heterogeneous nucleation as well as enhancement effects on PVDF.…”