Mechanochemical synthesis of chromium-based alloys

Mechanosynthesis and photophysics of colour-tunable photoluminescent group 13 metal complexes with sterically demanding salen and salophen ligands

“…3,4 In mechanochemistry, reactions between solids are promoted by applying mechanical energy, and reactions that oen are unfavourable or inaccessible in solutions can be readily performed. 5 The increasing momentum recently gained by the mechanochemical eld is illustrated by its widespread use in developing new reaction methodologies, 6,7 synthesis of organometallic complexes, 8,9 main group compounds, 10 metal-organic frameworks, 11 alloys, 12 composite materials, 13,14 and co-crystals. 15 It is worth mentioning that in some mechanochemical reactions, the use of minute amounts of solvent is unavoidable, especially in purications or workup, but this can be avoided in cases of high atomic efficiency or if the by-products can be removed by employing physical separation methods.…”

Fast and scalable solvent-free access to Lappert's heavier tetrylenes E{N(SiMe3)2}2 (E = Ge, Sn, Pb) and ECl{N(SiMe3)2} (E = Ge, Sn)

“…Hence, mechanosynthesis has been growing as powerful alternative to solution-based thermochemistry for the last two decades 4 in a wide range of elds. [5][6][7][8][9][10][11][12] However, it remains underrepresented across the main group element arena. 8,13 On the other hand, heavier carbene analogues, also known as heavier tetrylenes (HTs), are currently receiving increasing attention, not only for their rich and unique fundamental chemistry (small molecule activation, insertion into s-bonds, catalysis, etc.)…”

“…Hence, mechanosynthesis has been growing as powerful alternative to solution-based thermochemistry for the last two decades 4 in a wide range of fields. 5–12 However, it remains underrepresented across the main group element arena. 8,13…”

Mechanosynthesis and Photophysics of Colour-tunable Photoluminescent Group 13 Metal Complexes with Sterically Demanding 3,5-di-tert-butyl Substituted Salen and Salophen Ligands

“…3,4 In mechanochemistry, reactions between solids are promoted by the application of mechanical energy, and reactions that often are unfavourable or inaccessible in solutions can be readily performed. 5 The increasing momentum gained by the mechanochemical field is illustrated by its current widespread use in the development of new reaction methodologies, 6,7 synthesis of organometallic complexes, 8,9 main group compounds, 10 metal organic frameworks, 11 alloys, 12 composite materials, 13,14 and cocrystals. 15 .…”