Mechanochemically initiated copolymerizations. 7. Synthesis of copolymers based on styrene by vibratory milling.

Abstract

Copolymerization of styrene with maleic anhydride and isoprene was mechanochemically initiated by vibratory milling. The influence of time, comonomer ratio and addition of acceptors for radicals on the copolymerization process was investigated. The synthesized copolyniers were analyzed and the polymerization mechanism is discussed. 3lechnnochemisch initiierte Copolymerisat ion. 7. Die Synthese yon Styrencopolymeren durch Schwingmahlung

Shake, shear, and grind! – the evolution of mechanoredox polymerization methodology

“…In addition, due to mechanochemistry's unique ability to orthogonally transfer energy, it is rapidly being reevaluated as a useful method for polymer synthesis and upcycling processes traditionally performed in solution. [35][36][37][38][39][40][41][42][43][44]…”