Mechanochemically Synthesised Dicyanamide Hybrid Organic-Inorganic Perovskites and their Melt-Quenched Glasses

Abstract

Here we present efficient and scalable mechanochemical formation of hybrid organic-inorganic perovskites of the form [TPrA][M(dca)₃] (M = Mn²⁺, Co²⁺) and the subsequent formation of their bulk melt-quenched glass samples. The thermal, chemical and adsorptive properties of the materials are also investigated.