2024
DOI: 10.1038/s41467-024-46311-x
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Melt-quenched glass formation of a family of metal-carboxylate frameworks

Wen-Long Xue,
Guo-Qiang Li,
Hui Chen
et al.

Abstract: Metal-organic framework (MOF) glasses are an emerging class of glasses which complement traditional inorganic, organic and metallic counterparts due to their hybrid nature. Although a few zeolitic imidazolate frameworks have been made into glasses, how to melt and quench the largest subclass of MOFs, metal carboxylate frameworks, into glasses remains challenging. Here, we develop a strategy by grafting the zwitterions on the carboxylate ligands and incorporating organic acids in the framework channels to enabl… Show more

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Cited by 8 publications
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