“…Generally, melting of nanoparticles starts at their surfaces. Experimental techniques used to observe the melting of nanoparticles include for example X-ray [609,610] and electron diffraction [608,611,612], calorimetry [613], femtosecond laser spectroscopy [614] and surface Brillouin scattering [615]. Several reports have shown that samples of metal nanorods made of same material, but differing from each other in terms of average diameters and lengths, have dissimilar melting points.…”