SynopsisPorous membranes of poly(viny1 chloride) were obtained from cation exchange membranes prepared by the soaking and paste method, by selective decomposition of the cation exchange resin component. The structure and properties of the membranes as filters were investigated by scanning electron microscopy, infrared analysis, water permeability measurement, and determination of rejections for some solutes and dispersers with widely differing sizes. They completely rejected two kinds of bacteria and polymer particles with a diameter of about 0.1 pm. The rejection of hemoglobin ranged from 90 to loo%, depending upon the preparative conditions. Heat treatment of the cation exchange membranes increased water permeability of the resulting PVC porous membranes and decreased hemoglobin rejection in varying degrees, depending upon the treatment temperature.