Mercury(II) and silver(I) receptors based on tetrathiacalix[4]arene hydrazones

Podyachev, Sergey N.; Kashapova, Nadezda E.; Syakaev, Victor V.; Sudakova, Svetlana N.; Зайнуллина, Р. Р.; Грүнер, Маргит; Habicher, Wolf D.; Barsukova, T. A.; Yang, Fafu; Коновалов, А. И.

doi:10.1007/s10847-013-0307-0

Cited by 9 publications

(1 citation statement)

References 36 publications

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“…We have previously investigated the tetrathiacalix [4]arenes functionalized by tetraphenylhydrazone groups in the same range of metal ions. 50 The extraction selectivity of Ag + reached the similar value (S ¼ 18). In the case of podand 5 and pyrimidinophane 7a, the selective extraction of Ag + in the row of the investigated metal ions is much higher than for mentioned above compounds:…”

Section: Extraction Studiesmentioning

confidence: 84%

Metal binding properties of pyrimidinophanes and their acyclic counterparts

et al. 2014

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A series of acyclic and macrocyclic nucleobase derivatives that contain uracil and 2-thiocytosine units linked by polymethylene spacers was prepared. The length of spacers as well as the oxidation number of sulfur atoms entering into the structure of the compounds was varied. The crystal structure of pyrimidinophane with hexa-and heptamethylene linkers was established by X-ray analysis. The metal ion-binding properties of pyrimidinophanes and their acyclic counterparts were investigated by liquid extraction and 1 H NMR titration experiments. The compounds with 2-thiocytosine fragments revealed a high selectivity of extraction towards Ag + ions. The stoichiometry of silver complexes and the binding constants have been determined. The antibacterial activity of these complexes was also discussed.

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Section: Extraction Studiesmentioning

confidence: 84%