Merging single-electron transfer and energy transfer processes of photocatalyst: An atom economical strategy for the synthesis of 1-trifluoroethylated isoquinolines from cis and trans vinyl isocyanides

Liu, Yingle; Kang, Yunjie; Wang, Han; Dong, Yuting; Wei, Qinqin; Jiang, Yan; Yang, Yi; Gao, Haixiang

doi:10.1016/j.tetlet.2020.152348

Cited by 4 publications

(1 citation statement)

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“…[89] Worthy of note, the photoactivity of pyreneacyl sulfide was exploited to generate in situ a thioaldehyde in a visible-light induced Passerini multicomponent polymerization under very mild reaction conditions leading to soft matter materials. [90] Interestingly, S-containing heterocycles such thiophene have been shown to be suitable intramolecular traps for imidoyl radicals as shown in the formation of 1-trifluoroethyl isoquinolines 88 from vinyl isocyanide [91] 86 and in the photocatalyst-free addition/cyclization cascade of isocyanoheterobiaryl [63] 89 to give product 90 (Scheme 32).…”

Section: Miscellaneousmentioning

confidence: 99%

Sulfur‐Centered Radicals in Visible Light Isocyanide Photochemistry

Russo,

Brunelli,

Tron

et al. 2023

Eur J Org Chem

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Sulfur‐centered radicals have a key role in a plethora of synthetic organic transformations, whose scope has been further expanded thanks to the possibility to generate such species under visible light photocatalytic conditions. The current literature overview focuses on those transformations involving isocyanides and sulfur‐centered radicals with the aim to highlight the chemical space accessible, both in terms of complexity and diversity, and the mechanistic rational underpinning the current and future development of such chemical methodologies.

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