2012
DOI: 10.4067/s0717-97072012000400005
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meso-TETRAPHENYLIRONPORPHYRIN(III) CHLORIDE CATALYZED OXIDATION OF ANILINE AND ITS SUBSTITUENTS BY m-CHLOROPERBENZOIC ACID

Abstract: The most fascinating feature of heme-enzymes such as cytochromes P450 is their ability to carry out oxidations with high selectivity. Metalloporphyrin complexes are used as replicate compounds for cytochrome P450. A kinetic analysis has been carried out with the aim of understanding the mechanistic studies on oxidation of anilines by m-chloroperbenzoic acid catalyzed by meso-tetraphenylironporphyrin(III) chloride in aqueous acetic acid medium. The order of the reaction is found to be second order with respect … Show more

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