Abstract. The three neutral pseudoscalar mesons, 0 , and , represent one of the most interesting systems in strong interaction physics. A study of the electromagnetic properties of these mesons provides a sensitive probe of the symmetry structure of QCD at low energy. A comprehensive experimental program at Jefferson Laboratory (Jlab) is aimed at gathering high precision measurements on the two-photon decay widths and transition form factors at low Q 2 of 0 , and via the Primakoff effect. The completed experiments on the 0 radiative decay width at Jlab 6 GeV, and other planned measurements at Jlab 12 GeV will provide a rich laboratory to test the chiral anomaly and to study the origin and dynamics of chiral symmetry breaking at the confinement scale of QCD.