“…Comprehending the intricate relationship between the structure, defect nature, and electrical transport properties is paramount in the design of multifunctional semiconductors. Molybdates with the molecular formula X 2 MoO 4 , where X = Li, Tl, and Ag, have garnered significant attention within the scientific community due to their remarkable photocatalytic properties, 1,2 applications in scintillators, 3 sensors, [4][5][6] optical fibers, 7 as well as their outstanding performance in diverse applications such as antibacterial, 8 antifungal, 9 antiviral, 10 tribological, 11 microwave dielectric, 12 and supercapacitor electrode 13 applications. Furthermore, highly pure β-Ag 2 MoO 4 with a spinel-type cubic structure has been synthesized for catalysis applications due to its electronic properties.…”