Metabolic products of Fusarium larvarum fuckel. The fusarentins and the absolute configuration of monocerin

Grove, John Frederick; Pople, Michael

doi:10.1039/p19790002048

Cited by 61 publications

(42 citation statements)

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“…2, 158.1, 156.6, 144.2, 133.4, 108.0, 80.2, 79.5, 73.9, 61.8, 61.2, 56.2, 40.2, 38.3, 19.2, 14 9,150.6,142.4,132.5,107.8,107.5,83.8,78.5,72.4,61.0,56.1,40.8,38.1,19.2,14.1. (2S,3aS,7,3,3a,isochromen-5-one 31…”

Section: (Se)-1-(345-trimethoxyphenyl)hept-1-en-4-ol 25mentioning

confidence: 99%

Total synthesis of (+)-monocerin via tandem dihydroxylation-S_N2 cyclization and a copper mediated tandem cyanation–lactonization approach

2014

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Section: (Se)-1-(345-trimethoxyphenyl)hept-1-en-4-ol 25mentioning

confidence: 99%

Total synthesis of (+)-monocerin via tandem dihydroxylation-S_N2 cyclization and a copper mediated tandem cyanation–lactonization approach

2014

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“…Preparative TLC further differentiated the four compounds. Monocerin and its analogues were previously reported as antifungal compounds from fungal sources of Drechslera monoceras, Exserohilum monoceras, Helminthosporium monoceras, Exserohilum turcum, and Fusarium larvarum (Aldridge and Turner 1970;Robeson and Strobel 1982;Grove and Pople 1979;Claydon et al 1979). These secondary metabolites act on pathogens by interfering stages of divisional phases of cell cycle.…”

Section: Isocoumarinsmentioning

confidence: 99%

Natural Products as Fungicide and Their Role in Crop Protection

Santra

Banerjee

2020

Natural Bioactive Products in Sustainable Agriculture

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Seeking solutions from nature for solving one and all problems is the age-old practice for mankind, and natural products are proved to be the most effective one for keeping up the balance of development as well as the "healthy, wealthy, and well" condition of mother nature. Fungal pathogens are proved to be a common and popular contaminant of agroecosystem that approximately causes 70-80% of total microbial crop loss. To meet the proper global increasing need of food products as a result of population explosion, managing agricultural system in an eco-friendly and profitable manner is the prime target; thus the word "sustainable agriculture" plays it part, and this package is highly effective when coupled with nature-derived fungicidal products that can minimize the event of fungal infections in agrarian ecosystem. Present study enlists the most common and effective natural products that might be of plant or microbial origin, their mode of action, day-by-day development of phytopathogenic resistance against the prevailing fungicides, and also their role in maintenance of sustainability of agricultural practices with special emphasis on their acceptance over the synthetic or chemical one. A large number of bioactive compounds ranging from direct plant (both cryptogams algae and moss and phanerogams)-derived natural extracts, essential oil of aromatic plants, and low-molecular-weight antimicrobial compounds known as phytoalexins to secondary metabolites that are both volatile and nonvolatile organic compounds of microbes (fungal and actinobacterial members) residing inside the host tissue, called endophyte, are widely used as agricultural bioweapons. The rhizospheric partners of plant, mycorrhizae, are also a prime agent of this chemical warfare and protect their green partners from fungal invaders and emphasize the concept of "sustainable agriculture." 132

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“…Its enantiomer, the (S)-(+)-mellein (2, Figure 2), is also known as a natural product, but it is produced by few species of fungi compared with 1. In particular, compound 2 was firstly isolated from an unidentified fungus [14] and then from the cultures of the insect pathogen Fusarium larvarum, together with five other secondary metabolites [15].…”

Section: Melleins From Fungimentioning

confidence: 99%

Melleins—Intriguing Natural Compounds

Reveglia

Masi²,

Evidente³

2020

Biomolecules

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Melleins are 3,4-dihydroisocoumarins mainly produced by fungi, but also by plants, insects and bacteria. These specialized metabolites play important roles in the life cycles of the producers and they are involved in many biochemical and ecological processes. This review outlines the isolation and chemical and biological characterizations of natural-occurring melleins from the first report of (R)-mellein in 1933 to the most recent advances in their characterization in 2019. In addition, the pathways that could be involved in mellein biosynthesis are discussed, along with the enzymes and genes involved.

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Metabolic products of Fusarium larvarum fuckel. The fusarentins and the absolute configuration of monocerin

Abstract: Es werden die neuen Stoffwechselprodukte (I) und (IIa) isoliert.

Cited by 61 publications

References 0 publications

Total synthesis of (+)-monocerin via tandem dihydroxylation-S_N2 cyclization and a copper mediated tandem cyanation–lactonization approach

Total synthesis of (+)-monocerin via tandem dihydroxylation-S_N2 cyclization and a copper mediated tandem cyanation–lactonization approach

Natural Products as Fungicide and Their Role in Crop Protection

Melleins—Intriguing Natural Compounds

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Metabolic products of Fusarium larvarum fuckel. The fusarentins and the absolute configuration of monocerin

Abstract: Es werden die neuen Stoffwechselprodukte (I) und (IIa) isoliert.

Cited by 61 publications

References 0 publications

Total synthesis of (+)-monocerin via tandem dihydroxylation-SN2 cyclization and a copper mediated tandem cyanation–lactonization approach

Total synthesis of (+)-monocerin via tandem dihydroxylation-SN2 cyclization and a copper mediated tandem cyanation–lactonization approach

Natural Products as Fungicide and Their Role in Crop Protection

Melleins—Intriguing Natural Compounds

Contact Info

Product

Resources

About

Total synthesis of (+)-monocerin via tandem dihydroxylation-S_N2 cyclization and a copper mediated tandem cyanation–lactonization approach

Total synthesis of (+)-monocerin via tandem dihydroxylation-S_N2 cyclization and a copper mediated tandem cyanation–lactonization approach