Metal-Catalyzed Cyclization Reactions 1

Ma, Shuangshuang; Gao, Songsong; Alderson, Juliet M.; Beccalli, Egle M.; Bonetti, Andrea; Guiry, Patrick J.; Jammi, Suribabu; Mazza, Alberto; Nottingham, Chris; Phelps, Alicia M.; Schomaker, Jennifer M.; Shi, Min; Tang, Xuesong; Wang, D.; Yamamoto, Yasuhiro; You, Shu‐Li; Zhang, L.; Zhang, X.

doi:10.1055/b-003-129294

2016

DOI: 10.1055/b-003-129294

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Metal-Catalyzed Cyclization Reactions 1

Shuangshuang Ma¹,

Songsong Gao²,

Juliet M. Alderson³

et al.

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Mono‐Gold(I)‐Catalyzed Enantioselective Intermolecular Reaction of Ynones with Styrenes: Tandem Diels–Alder and Ene Sequence

Nanko

Inaba

Sekine

et al. 2021

Helvetica Chimica Acta

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Gold‐catalyzed intermolecular reaction leading to dihydronaphthalene derivatives in one pot from two equivalents of ynones with respect to styrene is uncovered. The [4+2] Diels–Alder cycloaddition of ynones and styrenes is catalyzed by a mono‐gold(I) complex and the conjugated acid to provide an unstable 3,8a‐dihydronaphthalene to subsequently undergo an intermolecular ene‐type reaction with the π‐activated ynone to afford multi‐component coupling dihydronaphthalene products. Linear relationships between chiral ligand‐gold complexes and chiral dihydronaphthalene products proves mono‐gold catalysis that triggers an asymmetric tandem Diels–Alder and ene reaction sequence.

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Mono‐Gold(I)‐Catalyzed Enantioselective Intermolecular Reaction of Ynones with Styrenes: Tandem Diels–Alder and Ene Sequence

Nanko

Inaba

Sekine

et al. 2021

Helvetica Chimica Acta

View full text Add to dashboard Cite

show abstract

Transition-metal-catalyzed cyclization reactions using vinyl and ethynyl benzoxazinones as dipole precursors

Yani

Xiao

et al. 2018

Tetrahedron Letters

123

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Metal-Catalyzed Cyclization Reactions 1

Cited by 2 publications

References 0 publications

Mono‐Gold(I)‐Catalyzed Enantioselective Intermolecular Reaction of Ynones with Styrenes: Tandem Diels–Alder and Ene Sequence

Mono‐Gold(I)‐Catalyzed Enantioselective Intermolecular Reaction of Ynones with Styrenes: Tandem Diels–Alder and Ene Sequence

Transition-metal-catalyzed cyclization reactions using vinyl and ethynyl benzoxazinones as dipole precursors

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