Metal‐Catalyzed Decarbenations by Retro‐Cyclopropanation

Mato, Mauro; Echavarren, Antonio M.

doi:10.1002/9783527829170.ch6

Transition Metal‐Catalyzed Carbene Transformations 2021

DOI: 10.1002/9783527829170.ch6

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Metal‐Catalyzed Decarbenations by Retro‐Cyclopropanation

Mauro Mato

Antonio M. Echavarren

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2024

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Cited by 2 publications

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Aromative Dephosphinidenation of a Bisphosphirane‐Fused Anthracene toward E−H (E=H, Si, N and P) Bond Activation

Luo,

Liu,

Huang

et al. 2024

Angewandte Chemie

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A bisphosphirane‐fused anthracene (5) was prepared by treatment of a sterically encumbered amino phosphorus dichloride (3) with MgA•3THF (A = anthracene). X‐ray diffraction analysis revealed a pentacyclic framework consisting of 5 with two phosphirane rings fused to the anthracene in a trans‐fashion. Compound 5 has been shown to be an efficient phosphinidene synthon, readily liberating two transient phosphinidene units for subsequent downstream bond activation via the reductive elimination of anthracene under mild conditions. The formal oxidative addition of H2 and E‐H (E = Si, N, P) bonds by the liberated phosphinidene provided diphosphine and substituted phosphines. Furthermore, phosphinidene transfer to alkenes and alkynes smoothly yielded the corresponding phosphiranes and phosphirenes. The mechanism of the H2 activation by 5 was investigated by density functional theory (DFT) calculations.

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Aromative Dephosphinidenation of a Bisphosphirane‐Fused Anthracene toward E−H (E=H, Si, N and P) Bond Activation

Luo,

Liu,

Huang

et al. 2024

Angewandte Chemie

View full text Add to dashboard Cite

show abstract

Aromative Dephosphinidenation of a Bisphosphirane‐Fused Anthracene toward E−H (E=H, Si, N and P) Bond Activation

Luo,

Liu,

Huang

et al. 2024

Angew Chem Int Ed

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show abstract

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Metal‐Catalyzed Decarbenations by Retro‐Cyclopropanation

Cited by 2 publications

References 71 publications

Aromative Dephosphinidenation of a Bisphosphirane‐Fused Anthracene toward E−H (E=H, Si, N and P) Bond Activation

Aromative Dephosphinidenation of a Bisphosphirane‐Fused Anthracene toward E−H (E=H, Si, N and P) Bond Activation

Aromative Dephosphinidenation of a Bisphosphirane‐Fused Anthracene toward E−H (E=H, Si, N and P) Bond Activation

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