2021
DOI: 10.25073/2588-1140/vnunst.5153
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Metal Complexes of π-expanded Ligand (5): Synthesis, Structural, and Photophysical Characterizations of Green-Red Luminescent Pyrene-based Salicylaldiminato-type Zinc Complexes

Abstract: A series of pyrene-based salicylaldimine-type ligands containing n-octyl or cyclohexyl or phenyl groups at imine nitrogen group, 1-hydroxy-2-[(N-substituted-imino)methyl]-pyrenes (octyl 1, cyclohexyl 1b and phenyl 1c), were synthesized and characterized. The ligands reacting with zinc acetate in the presence of sodium acetate gave the bis(salicylaldiminato)-type Zn(II) complexes, [bis[2-[(N-substituted-imino)methyl]-1-pyrenolato-N,O] zinc(II)] (octyl 1(Zn), cyclohexyl 1b(Zn), phenyl 1c(Zn)). The new ligands an… Show more

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