Metal dialkyl diselenophosphates:1 a rare example of co-crystallization with clusters, Ag8(μ8-Se)[Se2P(OPri)2]6 and Ag6[Se2P(OPri)2]6, superimposing in a trigonal lattice†

Liu, C. W.; Shang, Iu-Jie; Wang, Ju-Chung; Keng, Tai‐Chiun

doi:10.1039/a902429h

Cited by 50 publications

(19 citation statements)

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“…Of note, for the cocrystallization case between Ag 8 and Ag 12 , both clusters should be termed “nanocluster complexes” since they contain no free valence electrons. Of note, two nanocluster complex cocrystallization cases have also been previously reported, that is, (i) Ag 8 (μ 8 -Se)[Se 2 P(OPr i ) 2 ] 6 and Ag 6 [Se 2 P(OPr i ) 2 ] 6 and (ii) Cu 8 (μ 8 -Se)[S 2 P(OEt) 2 ] 6 and Cu 6 [S 2 P(OEt) 2 ] 6 ; both cluster complex pairs crystallized in a trigonal lattice. , …”

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confidence: 68%

“…Of note, two nanocluster complex cocrystallization cases have also been previously reported, that is, (i) Ag 8 (μ 8 -Se)[Se 2 P(OPr i ) 2 ] 6 and Ag 6 [Se 2 P-(OPr i ) 2 ] 6 and (ii) Cu 8 (μ 8 -Se)[S 2 P(OEt) 2 ] 6 and Cu 6 [S 2 P-(OEt) 2 ] 6 ; both cluster complex pairs crystallized in a trigonal lattice. 99,100 The reduction of Au−Ag−S 2 P(O i Pr) 2 complexes with NaBH 4 simultaneously yielded Au 0.5 Ag 0.5 @Ag 20 {S 2 P(O i Pr) 2 } 12 and Cl@Ag 8 {S 2 P(O i Pr) 2 } 6 nanoclusters (Figure 3). 90 Structurally, Cl@Ag 8 {S 2 P(O i Pr) 2 } 6 contained a hexahedral Cl@Ag 8 kernel, and each face of the hexahedron was capped by a S 2 P(O i Pr) 2 ligand (Figure 3a).…”

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Cocrystallization of Atomically Precise Nanoclusters

Kang

Zhu

2020

ACS Materials Lett.

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Of the great classes of nanocluster crystallization, "cocrystallization" has gained significant attention due to its elucidation of both intracluster structures and intercluster packing modes. In addition, the intermolecular interactions and resulting assembled constructs endow the cocrystallized materials with novel physical and chemical properties that differ from those of the individual components. Heterogeneous cocrystallization has recently emerged as a new "growth point" in nanocluster science. In this Perspective, we elaborate on relevant advances in studying the cocrystallization of metal nanoclusters. The packing patterns of the cocrystallized nanoclusters, as well as their geometric structures, are discussed case by case. In addition, the intercluster interactions among heterogeneous nanoclusters that account for the cocrystallization are also disclosed. The goal of this Perspective is to provide researchers attempting to study nanocluster cocrystallization with research fundamentals and to further propose some possible approaches (or new growth points) for the design and fabrication of cocrystallized cluster systems.

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confidence: 68%

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confidence: 99%

Cocrystallization of Atomically Precise Nanoclusters

Kang

Zhu

2020

ACS Materials Lett.

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“…[(RO) 2 PS 2 ] À anions are attached to all six faces of the cube with each sulfur atom bridging two silver atoms (42, only one face shown covered with the dithiophosphonate ligand). [174][175][176] In the series [Ag 11 (S/Se){(S/Se) 2 P(OR) 2 } 6 X 3 ] with X = halogen and R = alkyl the environment of the nonacoordinate chalcogenide anion is a tricapped trigonal prism, and the edges of this polyhedron are within the same range of Ag-Ag distances. The two silver atoms capping the trigonal faces are not close to the sulfur/selenium center (43).…”

Section: Silver Clustering At Sulfur and Seleniummentioning

confidence: 99%

Argentophilic Interactions

2014

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The decade 1990-2000 saw a growing interest in aurophilic interactions in gold chemistry. These interactions were found to influence significantly a variety of structural and other physical characteristics of gold(I) compounds. The attention paid to this unusual and counterintuitive type of intra- and intermolecular bonding between seemingly closed-shell metal centers has rapidly been extended to also include silver chemistry. Hundreds of experimental and computational studies have since been dedicated to the argentophilicity phenomenon. The results of this development are reviewed herein focusing on molecular systems where two or more silver(I) centers are in close contact leading to specific structural characteristics and a variety of novel physical properties. These include strongly modified ligand-to-metal charge-transfer processes observed in absorption and emission spectroscopy, but also colossal positive and negative thermal expansion on the one hand and unprecedented negative linear compressibility of crystal parameters on the other.

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“…[172,173] [172] Bei Verwendung der Single-und Multi-Referenz-Range-separated-DF-Stçrungstheorie bestätigten sich dieser Trend und auch die Ausnahmestellung von Cu. [173] [174][175][176] In der Reihe [Ag 11 (S/Se){(S/ Se) 2 P(OR) 2 } 6 X 3 ] mit X = Halogen und R = Alkyl befindet sich das neunfach koordinierte Chalkogenidanion in einer dreifach überdachten trigonal-prismatischen Umgebung, und die Kanten dieses Polyeders zeigen Ag···Ag-Abstände im Bereich um 3.0 . Die beiden Silberatome über den Dreiecksflächen befinden sich nicht in der Nähe des Schwefel-/ Selenzentrums (43).…”

Section: Bildung Von Silberclustern An Schwefel-und Selenatomenunclassified

Argentophile Wechselwirkungen

2014

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Zwischen 1990 und 2000 wuchs in der Goldchemie das Interesse an aurophilen Wechselwirkungen, nachdem man festgestellt hatte, dass diese eine Vielzahl struktureller und anderer physikalischer Eigenschaften von Gold(I)‐Verbindungen nennenswert beeinflussen. Die Aufmerksamkeit, die man diesem kontraintuitiven inter‐ und intramolekularen Typ von Bindung zwischen Metallzentren mit scheinbar abgeschlossener Elektronenschale entgegenbrachte, hat sich schnell auch auf die Chemie des Silbers ausgeweitet. Hunderte von Untersuchungen widmeten sich seither dem Phänomen der Argentophilie. Dieser Aufsatz gibt einen Überblick über diese Entwicklung mit Hauptaugenmerk auf molekularen Systemen mit zwei oder mehr in engem Kontakt stehenden Silber(I)‐Zentren, was zu spezifischen strukturellen sowie zu einer Vielzahl neuartiger physikalischer Eigenschaften führt. Diese schließen vor allem stark veränderte Ligand→Metall‐Ladungstransferprozesse ein, aber auch eine überdimensionale thermische Kontraktion auf der einen und eine beispiellose negative lineare Kompressibilität von Kristallparametern auf der anderen Seite.

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Metal dialkyl diselenophosphates:1 a rare example of co-crystallization with clusters, Ag8(μ8-Se)[Se2P(OPri)2]6 and Ag6[Se2P(OPri)2]6, superimposing in a trigonal lattice†

Cited by 50 publications

References 19 publications

Cocrystallization of Atomically Precise Nanoclusters

Cocrystallization of Atomically Precise Nanoclusters

Argentophilic Interactions

Argentophile Wechselwirkungen

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