Metal exchanged zeolites for catalytic decomposition of N2O

Experimental Research on Heterogeneous N2O Decomposition with Ash and Biomass Gasification Gas

“…all showed strong catalytic effect on N 2 O decomposition [9,12]. N 2 O decomposition rates reached 100% with Rh/Na 2 O/Al 2 O 3 as catalyst at a temperature of 425 °C.…”

“…The combustion of biomass, solid waste and coal in CFB can produce large amounts of ash. The influences of the different components in ash on N 2 O decomposition vary a lot [9,10]. Ca, Fe, Al and other metal oxides in circulating ash are considered as active ingredients.…”

The Effect of Co2+-Ion Exchange Time into Zeolite Y (FAU, Si/Al = 1.56): Their Single-Crystal Structures

“…-exchanged zeolite Y is well established efficient heterogeneous catalysts in industrial processes 1 and they have been extensively studied for the following applications: the epoxidation of styrene 2 and -pinene, 3 the disproportionation of CO, 4 the hydrodesulfurization reaction, 5 the reduction of NO, 6 the oxidation of benzyl alcohol 7,8 and methylene chloride and carbon tetrachloride, 9 the oxidative dehydrogenation of ethanol 10 and cyclohexene, 11 the ammoxidation of ethane, 12 the decomposition of N 2 O, 13 and the dehydration of ethanol. 14 To develop better Co 2+ catalysts, the positions, occupancies, and environments of Co 2+ ions in zeolites are of great interest in understanding their catalytic properties.…”

Metal Exchanged ZSM-5 Zeolite Based Catalysts for Direct Decomposition of N2O

“…They reported that Co-ZSM -5 containing Co in the framework had the highest activity for NO decomposition. Recently we have reported bimetal exchanged zeolites towards N 2 O decomposition [12]. Recent years have also seen a large number of publications, which are concerned with reducing the N 2 O emissions caused by the anthropogenic activities.…”