2012
DOI: 10.1007/s11368-012-0591-0
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Metal fluxes at the sediment–water interface in rivers in the Turvo/Grande drainage basin, São Paulo State, Brazil

Abstract: Purpose The Turvo/Grande drainage basin (TGDB), located in the northwestern region of São Paulo state, covers an area of 15,983 km 2 . The region is typically regarded as agricultural by the São Paulo State Environmental Agency, but the industrial area is expanding, and some studies have shown that metal concentrations in water can be higher than the values regulated by Brazilian law. Therefore, the aim of this study was to assess the role of sediments as a source or a sink of metals for drainage basin managem… Show more

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Cited by 13 publications
(15 citation statements)
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“…The concentrations of most of the metals in the SR pore water varied slightly, and the highest concentration was founded between 15-and 20-cm depth, except for Zn, which concentration was varied dramatically in all depths. Most of the metals were found at low concentrations in the top layers of the sediment (which correspond with the oxic zone), and higher metal concentrations were found in the deeper layers corresponding with the sub-oxic zones, and these results were similar to the results of other studies (Campanha et al 2012, Couture et al 2010, SantosEcheandia et al 2009). …”
Section: Resultssupporting
confidence: 90%
“…The concentrations of most of the metals in the SR pore water varied slightly, and the highest concentration was founded between 15-and 20-cm depth, except for Zn, which concentration was varied dramatically in all depths. Most of the metals were found at low concentrations in the top layers of the sediment (which correspond with the oxic zone), and higher metal concentrations were found in the deeper layers corresponding with the sub-oxic zones, and these results were similar to the results of other studies (Campanha et al 2012, Couture et al 2010, SantosEcheandia et al 2009). …”
Section: Resultssupporting
confidence: 90%
“…Sedimentary diagenetic processes across the sediment-water interface, such as diffusion, migration, and transformation, are significantly driven by redox geochemistry, and Mn or Fe could be a good indicator to reveal the status of sedimentary redox conditions (oxic, sub-oxic, or anoxic conditions; Kalnejais et al 2015). The peaks of Mn in the profiles show that the redox conditions facilitate the reductive dissolution of a fraction of Mn oxyhydroxide particles and their release into pore water (Campanha et al 2012). The thicknesses of suboxic layers from the northern bays (about 2-3 cm) were thinner than that (about 5 cm) at the central lake (CL) site.…”
Section: Resultsmentioning
confidence: 99%
“…The profiles of Ni and Zn at ZS showed concentrations progressively decreasing from top to bottom without showing layers of pronounced spikes in concentrations. Thus, these characteristics may be attributed to some other factors such as pH, redox conditions, sulfide concentration, occurrence of complexants, and dissolved organic carbon, which may have controlled the mobility of metals in the deeper layer of pore water, and these processes needed further research to identify other processes that govern metal mobility (Campanha et al 2012;Point et al 2007).…”
Section: Resultsmentioning
confidence: 99%
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“…• absorption by suspended particulate matter, co-precipitation, desorption (Campanha et al, 2012) and…”
Section: Arsenic Mobilisationmentioning
confidence: 99%